An electron drops from the second energy level to the first energy level within an excited hydrogen atom (a) determine the energy of the photon emitted (b) calculate the frequency of the photon emitted (c) calculate the wavelength of the photon emitted. (Answer: (a) 10.2 eV (b) 2.5 x 10¹⁵ Hz (c) 120 nm) 



Given Data:

 Atom: Hydrogen

Excited state = n = 2

Lower state = p = 1


To Find:

(a) Energy of the photon emitted = E  ?

(b) Frequency of the photon emitted f  ?

(c) Wavelength of the photon emitted = λ ?



Solution:


(a) Energy of the photon emitted E  ?

The energy of the photon emitted is given by:

E = EnEn - EpEp -------------(1)




Where EnEn is the energy of an electron in an excited state and EpEp is the energy of an electron in the lowest state.


EnEn = -E0n2E0n2


Where E0E0 = constant = 13.6 eV and n = 2 So,




EnEn = - 13.6eV2213.6eV22


EnEn = - 13.6eV413.6eV4


EnEn = - 3.4 eV


and


EpEp = -E0p2E0p2


Where E0E0 = constant = 13.6 eV and p = 1 So,




EpEp = - 13.6eV1213.6eV12


EpEp = - 13.6eV113.6eV1


EpEp = - 13.6 eV


Now putting values in Equation (1)

E EnEn - EpEp  = - 3.4 eV - (- 13.6 eV ) = 10.2 eV

E = 10.2 eV -------------------Ans.1



(b) Frequency of the photon emitted f  ?

We know that 

E = hf

or 

 f EhEh

By putting values of E = 10.2 eV = 10.2 x 1.6 x 10⁻¹⁹ J and Plank's Constant = h =  6.62 x 10⁻³⁴ m² kg s⁻¹

 f 10.21.610¹J6.6210³m²kgs¹

By simplifying we get 

f 2.46 x 10¹⁵ Hz -------------------Ans.2


(c) Wavelength of the photon emitted λ =  ?

we know that v = f λ, where v = c = 3 x 10⁸ m s⁻¹

or

λ = 310ms¹2.4610¹Hz

λ = 1.219 x 10⁻⁷ m 

or

λ = 121.9 x 10⁻⁹ m 

λ = 121.9  nm ------------------Ans.3




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