Find the wavelength associated with an electron in the state n=4 of hydrogen. (Answer: 1.33 nm) 



Given:

Atom: Hydrogen

Energy level n = 4

∴ Plank's Constant = h =  6.62 x 10⁻³⁴ m² kg s⁻¹

∴ Mass of the electron = m = 9.11 x 10⁻³¹ kg

∴ Charge on the electron = e = 1.6 x 10⁻¹⁹ C

∴ Coulomb's Constant  = K = 9 x 10⁹ N m² C⁻²


To Find:


The wavelength associated with electron λ =  ?


Solution:

The  formula for wavelength is 

 λ = h2mEn

Where

En = 
2π²k²men²h²  So,

 λ = h2m2π²k²men²h²

 λ = h2mπke²nh

or

 λ = nh²2mπke²

by putting the corresponding values 



 λ = 4(6.6210³m²kgs¹)²29.1110³¹kg3.1416910Nm²C²(1.610¹C)²


 λ 443.824410mkg²s²515.15956810²²kgNm²C²2.5610³C²

[N = kg m s⁻²]

 λ = 175.297610mkg²s²1318.8084940810kgms²kgm²

or

 λ = 0.1329x 10⁻⁸ m

or

 λ = 1.329x 10⁻⁹ m

Or

 λ = 1.329 nm  ---------------Ans.

Thus the wavelength associated with an electron in the state n=4 of hydrogen is 121.9  nm  



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