Find the wavelength of the spectral line corresponding to the transition in hydrogen from n = 6 state to n = 3 states. (Ans: 1094 nm)
Data Given:
Excited state = n = 8
Lower state = p = 1
∴ Rydberg constant = R = 1.097 x 10⁷ m⁻¹
To Find:
The wavelength of the spectral line = λ = ?
>
1λ = R( 1p²-1n²)
1λ = 1.097 x 10⁷ m⁻¹ ( 19-136)Solution:
Using the Rydberg formula for electron transition from excited state p to lover state n
by putting values
1λ = 1.097 x 10⁷ m⁻¹ ( 13²-16²)
1λ = 1.097 x 10⁷ m⁻¹ 4-136
1λ = 1.097 x 10⁷ m⁻¹ 336
1λ = 1.097x10⁷m⁻¹12
by flipping the fraction on both sides of the equation we get
λ = 121.097x10⁷m⁻¹
or
λ = 10.938 x 10⁻⁷ m
or
λ = 1093.8x 10⁻⁹ m
λ = 1094 nm ------------Ans.
Extra Calculation:
Or (expressing in Angstrom)
λmin = 10938 x 10¹⁰ m
λmin = 10938 A°
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